Measurement of Isobaric Vapor-Liquid Equilibrium for Binary System β- Caryophyllene + Linalool and Eugenol + Linalool at 30 and 60 kPa

Fachrizan Bilal Masrur, Mauludandru Heradiprakoso, Rizky Tetrisyanda, Kuswandi Kuswandi

Abstract


The Vapor-Liquid Equilibrium experiment conducted for the final project focused on studying thermodynamic behavior of Eugenol, Beta-caryophyllene, and Linalool during their vapor and liquid phases. These compounds were chosen due to their significance in various industries, including pharmaceuticals, cosmetics, and flavorings. Equilibrium data between mixtures is still very limited in various conditions. The experiment tested on Othmer still that has been modified and validated corresponds to the vapor pressure data of each component using the equation of Antoine and Wagner-Ambrose obtained Average Absolute Deviation (AAD) T of 0,424% and 0,246%. This study aimed to obtain vapor-liquid equilibrium data for binary systems, which are Eugenol + Linalool and Beta-Caryophyllene + Linalool at 30 kPa and 60 kPa with a mole composition range (x1) from 0—1 for each pressure. Equilibrium data will be correlated with Wilson, Non Random Two-Liquid (NRTL), dan Portmanteau of Universal Quasichemical (UNIQUAC) model equations to represent all experiment data. The results of this study obtained the AAD values for each system β-Caryophyllene + Linalool and Eugenol + Linalool at a pressure of 30kPa and 60 kPa were below 0,5%

Keywords


Eugenol; Industry; Linalool; Thermodynamic Correlations; Vapor-Liquid Equilibrium; β-Caryophyllene

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References


E. Herlina, D. Widiastuti and A. Triadi, "Potensi Minyak Atsiri Bunga Kenanga (Cananga Odorata) Sebagai Antibakteria Dalam Sediaan Hand Sanitizer Gel," Ekologia: Jurnal Ilmiah Ilmu Dasar Dan Lingkungan Hidup, pp. 88-94, 2020.

F. Anggia, Yuharmen and Balatif, "Perbandingan Isolasi Minyak Atsiri dari Bungan Kenangan (Cananga Odorata) Cara Konvensional dan Microwave serta Uji Aktivitas Antibakteri dan Antikosidan," Jurnal Online Mahasiswa Fakultas Matematika Dan Ilmu Pengetahuan Alam Universitas Riau, 2014

M. Firdaus, "Identifikasi Komponen Minyak Atsiri Bunga Kenangan (Cananga Odorata) dan Uji Efektivitas Aromaterapi Secara In Vivo", Repository Universitas Islam Negeri Ar-Raniry Banda Aceh, 2022.

J. Budi, N. Damayanti, Y. Dhani and N. Dewi, "Ekstraksi dan Karakterisasi Minyak Atsiri Bunga Kenangan (Cananga Odorata) dan Aplikasinya Sebagai Penolak Nyamuk pada Lotion dan Parfum," Jurnal Kimia, 2018.

E. A. Ahmed, H. A. Zahra, R. B. Ammar, M. E. Mohamed and H.-I. M.Ibrahim, "Beta-Caryophyllene Enhances the Anti-Tumor Activity of Cisplatin in Lung Cancer Cell Lines through Regulating Cell Cycle and Apoptosis Signaling Molecules," MDPI, vol. 27, 2022.

V. H. S. Rodrigues, R. N. Almeida, R. M. Vargas and E. Cassel, "Vapor pressure and vapor-liquid equilibrium data for eugenol/caryophyllene binary system at low pressures by experimental and predictive methods," The Journal of Chemical Thermodynamics, vol. 168, 2022.

K. Kuswandi, G. Wibawa, I. Hidayatulloh, C. Mahardhikawati and A. D. Pratiwi, "Ternary liquid-liquid equilibria for β-caryophyllene(1) + 1-propanol(2) + water(3) system at temperatures 303.15, 313.15, and 323.15 K," in IOP Conference Series: Materials Science and Engineering, 2018.

I. Hidayatullah, A. Wiguno and K. Kuswandi, "Isobaric Vapor-Liquid Equilibria for Binary," IPTEK: The Journal of Engineering, vol. 5, 2019.

H. A. Ekasanti, E. P. Hermawati, A. Wiguno and K. Kuswandi, "Prediksi Kesetimbangan Uap-Cair Sistem Biner Etanol + Eugenol dan 1-Propanol + Eugenol pada Berbagai Tekanan," Repository ITS, Surabaya, 2018.

N. Nehemia and L. A. M. Wiyasa, "Kesetimbangan Cair-Cair Sistem Terner Eugenol + β – Caryophyllene + Larutan Naoh pada Temperatur 303,15 K dan pada Tekanan Atmosferik," Repository ITS, Surabaya, 2018.

S. M. García-Abarrio, L. Haya, J. I. Pardo, J. S. Urieta and A. M. Mainar, "Isobaric VLE of the mixture {(±)-linalool + ethanol}: A case study for the distillation of absolute and volatile oils," The Journal of Chemical Thermodynamics, vol. 64, pp. 182-186, 2013.

Lisdiana and Nuraini, "Potensi Eugenol Sebagai Agen Proteksi Kerusakan Struktur Paru Akibat Paparan Asap Rokok," Indonesian Journal of Mathematics and Natural Science, vol. 41, 2018.

C. Ghelardi, N. Galeotti, L. Di Cesare Mannelli, G. Mazzanti and A. Bartolini, Local anaesthetic activity of b-caryophyllene, Farmaco, 2001.

R. Raguso, "More lessons from linalool: insights gained from a ubiquitous floral volatile," Current Opinion in Plant Biology, vol. 32, pp. 31-36, 2016.

J. M. Smith, H. C. Van Ness, M. M. Abbott and M. T. Swihart, Introduction to Chemical Engineering Thermodynamics Eighth Edition, 8th ed., New York: McGraw-Hill Education, 2018.

J. R. Elliott and C. T. Lira, Introductory Chemical Engineering Thermodynamics Second Edition, Prentice Hall, 2012.

R. Wittig, J. Lohmann and J. Gmehling, "Vapor-liquid equilibria by UNIFAC Group Contribution. 6. Revision and Extension," Industrial & Engineering Chemistry Research, pp. 183-188, 2003.




DOI: http://dx.doi.org/10.12962/j2964710X.v4i2.19180

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