"Water-In-Salt" Electrolyte For High Temperature Aluminum Ion Battery Application
Abstract
This study focuses on examining aluminum chloride hexahydrate (AlCl3·6H2O) as an electrolyte salt in an Aluminum Ion Battery. The goal is to assess the effectiveness of AlCl3·6H2O as an electrolyte in an Aluminum Ion Battery, evaluate the battery's performance, and examine the anode and cathode properties of an Aluminum Ion Battery. Laboratory tests and literature analysis are the approaches used. Following cyclic voltammetry testing, it was shown that the water-in-salt electrolyte AlCl3 performed better than the 1M AlCl3 electrolyte. Compared to the 1M AlCl3 electrolyte, the hydrogen evolution reaction in the water-in-salt electrolyte AlCl3 has a smaller potential range. The cyclic voltammetry graph of an aluminum ion battery containing a water-in-salt AlCl3 electrolyte is noticeably smaller than that of an aluminum ion battery with a 1M AlCl3 electrolyte. It has been observed that the water-in-salt AlCl3 electrolyte requires more activation energy compared to the 1M AlCl3 electrolyte. Based on SEM-EDS data, using water-in-salt electrolyte AlCl3 for aluminum ion batteries is better as it does not cause significant defects in the anode and cathode.
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S. A. Pradanawati, F.-M. Wang, and J. Rick, “In situ formation of pentafluorophosphate benzimidazole anion stabilizes high-temperature performance of lithium-ion batteries,” Electrochimica Acta, vol. 135, pp. 388–395, 2014.
W. Pan, Y. Wang, Y. Zhang, H. Y. H. Kwok, M. Wu, X. Zhao, and D. Y. Leung, “A low-cost and dendritefree rechargeable aluminium-ion battery with superior performance,” Journal of Materials Chemistry A, vol. 7, no. 29, pp. 17420–17425, 2019.
M. Angell, C.-J. Pan, Y. Rong, C. Yuan, M.-C. Lin, B.-J. Hwang, and H. Dai, “High coulombic efficiency aluminum-ion battery using an alcl3-urea ionic liquid analog electrolyte,” Proceedings of the National Academy of Sciences, vol. 114, no. 5, pp. 834–839, 2017.
N. Jayaprakash, S. Das, and L. Archer, “The rechargeable aluminum-ion battery,” Chemical Communications, vol. 47, no. 47, pp. 12610–12612, 2011.
K. B. Lee, “Urine-activated paper batteries for biosystems,” Journal of Micromechanics and Microengineering, vol. 15, no. 9, p. S210, 2005.
I. F. Antika and S. Hidayat, “Karakteristik anoda baterai lithium-ion yang dibuat dengan metoda spraying berbasis binder cmc,” JIIF (Jurnal Ilmu dan Inovasi Fisika), vol. 3, no. 2, pp. 114–121, 2019.
R. Chang, Chang, Chemistry c 2010, 10e, Student Edition (Reinforced Binding). AP CHEMISTRY
CHANG, McGraw-Hill Education, 2009.
Z. Yu, S. Jiao, S. Li, X. Chen, W.-L. Song, T. Teng, J. Tu, H.-S. Chen, G. Zhang, and D.-N. Fang, Flexible stable solid-state al-ion batteries,” Advanced functional materials, vol. 29, no. 1, p. 1806799, 2019.
N. Elgrishi, K. J. Rountree, B. D. McCarthy, E. S. Rountree, T. T. Eisenhart, and J. L. Dempsey, “A practical beginner’s guide to cyclic voltammetry,” Journal of chemical education, vol. 95, no. 2, pp. 197–206, 2018.
I. Smoljko, S. Gudi´c, N. Kuzmani´c, and M. Kliški´c, “Electrochemical properties of aluminium anodes for al/air batteries with aqueous sodium chloride electrolyte,” Journal of applied electrochemistry, vol. 42, pp. 969–977, 2012.
Y. A. Cengel and M. Boles, “Thermodynamics (in si units): An engineering approach,” 2014.
D. Linden and T. B. Reddy, “Handbook of batteries 3 ed. amerika serikat: The mcgraw-hills companies,” 2002.
S. Priyono, M. A. Dhika, K. Sebayang, A. Subhan, and B. Prihandoko, “Pembuatan anoda li4ti5o12 dan studi pengaruh ketebalan elektroda terhadap performa elektrokimia baterai ion lithium,” 2016.
J. Kohout, “Modified arrhenius equation in materials science, chemistry and biology,” Molecules, vol. 26, no. 23, p. 7162, 2021.
G. Zhu, M. Angell, C.-J. Pan, M.-C. Lin, H. Chen, C.-J. Huang, J. Lin, A. J. Achazi, P. Kaghazchi, B.-J. Hwang, et al., “Rechargeable aluminum batteries: effects of cations in ionic liquid electrolytes,” RSC advances, vol. 9, no. 20, pp. 11322–11330, 2019.
DOI: http://dx.doi.org/10.12962/j25807471.v7i2.18477
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