Degradation of Methylene Blue Using Sodalite from Natural Clay Impregnated Fe

Firdaus Malik

Abstract


The purpose of this study was to utilize the potential of natural clay in the Riau, synthesized into sodalite to degrade methylene blue dye. Synthesis of natural clay sodalite has been carried out using the reflux method. The clay was leached using 3 M H2SO4 for 3 hours, calcination at 750oC for 3 hours, then aging with 5 M NaOH for 7 hours at 80 oC with a magnetic stirrer stirring and refluxed for 8 hours at 100oC, then impregnated using FeCl3.6H2O and calcined at 300oC for 4 hours. Based on the diffractogram the formation of sodalite is indicated by a peak 2θ = 14.117°; 19.743°; 24.598°; 31.927° dan 35.082°. The results of the sodalite micrograph are spherical irregular, Based on the results of the degradation process of methylene blue by sodalite/Fe-clay Maredan and the highest percentage of methylene blue decolorization was 99.98%.


Keywords


Kimia Fisika

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References


Oruc, Z, Ergut, M, Uzuno, D, Ozer, A, “Green Synthesis Of Biomass-Derived Activated Carbon/Fe-Zn Bimetallic Nanoparticles From Lemon (Citrus Limon (L.) Burm.F.) Wastes for Heterogeneous Fenton-Like Decolorization of Reactive Red 2,” Journal of Environmental Chemical Engineering, vol. 7 pp. 103-231, 2019.

Hassan, H and Hameed, B, H, “Fe-Natural Zeolite as Highly Active Heterogeneous Catalyst in Decolorization of Reactive Blue 4”, International Journal of Environmental Science and Development, Vol. 11, No. 3, 2020.

Benatti, C. T and Tavares, C. R. G, “Fentons Process for the Treatment of Mixed Waste Chemicals”, Universidade Estadual de Maringa, UEM, Brazil, 2012

Dyer, A, “An Introduction to Zeolite Molecular Sieves”, John Wiley and Sons Ltd, Chichester, England, 1988.

Thuadij, P dan Mukda, P. Synthesis and characterization of zeolite derived from buriram sugarcane bagasse ash and narathiwat kaolinite. Journal of Science and Technology, vol. 8(3), pp. 320-326, 2016.

Zhang, Q, Wang, Q dan Wang, S, “Efficient Heterogeneous Fenton-Like Catalysis of Fe-Doped SAPO-44 Zeolite Synthesized From Bauxite and Rice Husk”, Chemical Physics Letters, vol 753, pp. 137-598, 2020.

Liu, G, Wang, Y, Zhang, Y, Xu, X, Qi, X, Wang, H, “Modification of Natural Zeolite and its Application To Advanced Recovery Organic Matter From an Ultra-Short-SRT Activated Sludge Process Efflue”, Science of the Total Environment, vol. 652, pp. 1366–1374, 2019.

Singh, L, Rekha, P and Chand, S, "Cu-Impregnated Zeolite Y as Highly Active and Stable Heterogeneous Fenton-Like Catalyst for Degradation ff Congo Red Dye”, Separation and Purification Technology, vol. 170, pp. 321–336, 2016

Azmi, N. H. M., Ayodele, O. B., Vadivelu, V. M., Asif, M., dan Hameed, B. H, “Journal of The Taiwan Institute of Chemical Engineers Fe- modified Local Clay as Effective and Reusable Heterogeneous Photo- Fenton Catalyst for The Decolorization of Acid Green 25”, Journal of the Taiwan Institute of Chemical Engineers, vol. 03 : 02, 2014.

Anita, S dan Itnawita, “Karakterisasi zeolit dari mineral kaolin yang berasal dari desa Sencalang kabupaten Indra Giri Hilir”, Jurnal Proton, vol. 4(2), pp. 1-2, 2014.

Esfandian, H, Fakhraee, H dan Azizi, A, ”Removal of strontium ions by synthetic nano sodalite zeolite from aqueous solution”, International Journal of Engineering, vol. 29(2) pp. 160-169, 2016.

Bohacs, K, Faitli, J, Bokanyi, L dan Mucsi, G, “Control natural zeolite properties by mechanical activation in stirred media mill”, Journal of Archieves of Metallurgy and Material vol. 62(1), pp. 1399-1406, 2017.

Nidheesh, P. V., dan Gandhimathi, R. Degradation of Dyes From Aqueous Solution By Fenton Processes : A Review. Environ Sci Pollut Res. Department of Civil Engineering, National Institute of Technology, Tiruchirappalli, Tamil Nadu, India. 1-34, 2013.

Wang, S, ”Comparative Study of Fenton-like Reaction Kinetics In Decolourisation of Wastewater”, Dye and Pigment, Vol.76, pp. 714- 720, Australia, 2008.




DOI: http://dx.doi.org/10.12962/j25493736.v5i2.7872

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