The effect of doping of La3+ ions on multiferoic Bi2-xLaxFe4O9 (x = 0; 0.2; 0.5; 1.0) as microwave absorber

yohanes edi gunanto, Wisnu Ari Adi

Abstract


The synthesis and characterization of Bi2-xLaxFe4O9 multiferoic material (x = 0; 0,2; 0,5; 1) have been used as microwave absorbers. Bi2-xLaxFe4O9 (x = 0; 0,2; 0.5; 1) material was made by solid state reaction with mechanical milling technique using high energy milling (HEM). X-ray diffraction (XRD) was used for characterization of formation phase and crystal structure, scanning electron microscopy-energy dispersive spectra (SEM-EDS) was used to characterize surface morphology and particle size, whereas vector network analysis (VNA) was used for characterization of absorption capability microwaves. The characterization results showed that all samples were in phase with orthorombic crystal structure, P bam space group. The average particle size was 578.5 nm with an almost homogeneous form. Meanwhile, the best sample in absorbing microwaves was obtained for x = 0.2 with reflection loss value (RL) around -21dB at 11.2 GHz frequency

Keywords


crystal structure; microwave absorption; multiferroic; reflection loss.

Full Text:

PDF

References


A. K. Pradhan, K. Zhang, D. Hunter, J. B. Dadson, G. B. Loutts, P. Bhattacharya, R. Katiyar, Jun Zhang, D. J. Sellmyer, U. N. Roy, Y. Cui, and A. Burger, Magnetic and electrical properties of single-phase multiferroic BiFeO3, Journal of Applied Physics 97, 093903 (2005).

K. GUO, R. Zhang, T. He, H. Kong, and C. Deng, Multiferroic and in-plane magnetoelectric coupling properties of BiFeO3 nano-films with substitution of rare earth ions La3+ and Nd3+, Journal of Rare Earths Volume 34, Issue 12, Pages 1228-1234 (December 2016).

S Bi, J Li, B Mei, X J Su, C Z Ying and P H Li, Effect of Zn doping on the microwave absorption of BFO multiferroic materials, IOP Conf. Series: Materials Science and Engineering 292, 012105 doi:10.1088/1757-899X/292/1/012105 (2017).

S. Li, R Nechache, I. A. V. Davalos, G. Goupil, L. Nikolova, M. Nicklaus, J. Laverdiere, A. Ruediger, and F. Rosei, Ultrafast microwave hydrothermal synthesis of BiFeO nanoplates, J. Am. Ceram. Soc., 96 [10] 3155–3162, DOI: 10.1111/jace.12473 (2013).

Y. Li, X. Fang, M. Cao, Thermal frequency shift and tunable microwave absorption in BiFeO3 family, Scientific Reports Volume 6, Article number: 24837 (2016).

J. Zhao, T. Liu, Y. Xu, Y. He, and W. Chen, Synthesis and characterization of Bi2Fe4O9 powders, Journal of Materials Chemistry and Physics 128, 388-391 (2018).

H. Yang, J. Dai, L. Wang, Y. Lin, F. Wang, and P. Kang, A novel approach to prepare Bi2Fe4O9 flower-like spheres with enhanced photocatalytic performance, Scientific Reports 7 doi:10.1038/s41598-017-00831-3 (2017).

M. Santhiya, K. S. Pugazhvadivu, K. Tamilarasan, and C. Rangasami, Influence of sputtering power on the structure and electrical properties of Bi2Fe4O9 thin film, Acta Metall. Sin. (Engl. Lett.) doi:10.1007/s40195-017-0537-z (2017).

A. Kirsch, M. M. Murshed, P. Gaczynski, K. –D. Becker, and T. M. Gesing, Bi2Fe4O9: structural changes from nano-to micro-crystalline state, Z. Naturforsch 71(5)b 447-455 (2016).

X. Yuan, L. Shi, J. Zhao, S. Zhou, and J. Guo, Tunability of magnetization and bandgap in mullite-type Bi2Fe4O9 ceramics through non-magnetic ions, Scripta Materialia 146 55-59 (2018).

S. R. Mohapatra, S. D. Kaushik, and A. K. Singh, Enhanced antiferromagnetic transition and magnetodielectric study in cobalt and holmium co-subtituted multiferroic Bi2Fe4O9, Mater. Res. Express 5 016107 (2018).

M. Ahmadzadeh, A. Ataie, E. Mostafavi, The effects of mechanical activation energy on the solid-state synthesis process of BiFeO3, Journal of Alloys and Compounds 622 548–556 (2015).




DOI: http://dx.doi.org/10.12962/j24604682.v16i2.5739

Refbacks

  • There are currently no refbacks.


Creative Commons License
This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.