A Mass Ratio of Hierarchical H-ZSM5 And Fatty Acid Methyl Ester of Cerbera Manghas Oil and The Effect on The Hydrocarbon Liquid Product Composition

Sutrisno Sutrisno, Rahmi Rahmi, Lenny Marlinda, Muhammad Al Muttaqii, Cyndy Dwi Afrila, Yanuar Fasmawi, Yuli Evrianti

Abstract


Fossil fuels are classified as non-renewable resources. On the other hand, using fossil fuels has further aggravated the impact of the environmental crisis. The development of alternative fuels that are renewable and renewable is urgently needed in line with the increasing need for fuel. One alternative energy source that can be used in the development of biofuels is Cerbera manghas oil. The catalytic cracking process with 178 g of Cerbera manghas oil can be carried out using hierarchical H-ZSM-5 as a catalyst with a mass of 0.1, 0.2, 0.3, 0.4, and 0.5g at a temperature of 250℃. Gas Chromatography Analysis–Mass Spectrometry (GC-MS) was performed on Cerbera manghas oil and biofuel products. Several hydrocarbons, C7-C12 and C16-C17, with the largest content, were identified as diesel (29.14%) and gasoline (14.08%) using a catalyst mass of 0.5g. So that the use of hierarchical H-ZSM-5 catalyst in the catalytic cracking of Cerbera manghas oil can produce hydrocarbon range gasoline.

Keywords


Biofuel; Cracking; Cerbera Manghas Oil; Fatty Acid Methyl Ester; H-ZSM-5

Full Text:

Full Text

References


Budianto A, Sumari S, Pambudi W, Andriani N, Mardianto A. Performance Test of Zn HZSM-5/-alumina catalyst in Biofuel Production from RBD Stearin as a Substitute for Fossil Fuels. In: Proceedings of the 13th International Interdisciplinary Studies Seminar, IISS 2019, 30-31 October 2019, Malang, Indonesia Malang, Indonesia: EAI; 2020. p. 624–636. https://doi.org/10.4108/eai.23-10-2019.2292995.

Al-Muttaqii M, Kurniawansyah F, Prajitno DH, Roesyadi A. Hydrocracking of Coconut Oil over Ni-Fe/HZSM-5 Catalyst to Produce Hydrocarbon Biofuel. Indonesian Journal of Chemistry 2019 apr;19(2):319. https://doi.org/10.22146/ijc.33590.

Riyanto T, Istadi I, Buchori L, Anggoro DD, Nandiyanto ABD. Plasma-assisted catalytic cracking as an advanced process for vegetable oils conversion to biofuels: A mini review. Industrial and Engineering Chemistry Research 2020;59(40):17632–17652.

Ibrahim MA, El-Araby R, Abdelkader E, Saied ME, Abdelsalam AM, Ismail EH. Waste cooking oil processing over cobalt aluminate nanoparticles for liquid biofuel hydrocarbons production. Scientific reports 2023 12;13(1):3876.

Marlinda L, , Muttaqii MA, Roesyadi A, and. Production of Biofuel by Hydrocracking of Cerbera Manghas Oil Using Co-Ni/HZSM-5 Catalyst : Effect of Reaction Temperature. The Journal of Pure and Applied Chemistry Research 2016 sep;5(3):189–195. https://doi.org/10.21776/ub.jpacr.2016.005.03.254.

Prajitno DH, Marlinda L, Al-Muttaqii M, Gunardi I, Roesyadi A. Hydrocracking of Cerbera manghas Oil with CoNi/HZSM-5 as Double Promoted Catalyst. Bulletin of Chemical Reaction Engineering & Catalysis 2017 aug;12(2):167. https://doi.org/10.9767/bcrec.12.2.496.167-184.

Atabani AE, Silitonga AS, Ong HC, Mahlia TMI, Masjuki HH, Badruddin IA, et al. Non-edible vegetable oils: A critical evaluation of oil extraction, fatty acid compositions, biodiesel production, characteristics, engine performance and emissions production. Renewable and Sustainable Energy Reviews 2013 feb;18:211–245. https://doi.org/10.1016/j.rser.2012.10.013.

Tambun R, Gusti ON, Nasution MA, Saptawaldi RP. Biofuel Production from Palm Olein by Catalytic Cracking Process Using ZSM-5 Catlyst. Jurnal Bahan Alam Terbarukan 2017 jun;6(1):50–55. https://doi.org/10.15294/jbat.v6i1.8733.

Ong HC, Silitonga AS, Mahlia TMI, Masjuki HH, Chong WT. Investigation of biodiesel production from cerbera manghas biofuel sources. Energy Procedia 2014;61:436–439.

Aini AN, Al-Muttaqii M, Roesyadi A, Kurniawansyah F. Performance of ni-cu/hzsm-5 catalyst in hydrocracking process to produce biofuel from cerbera manghas oil. Key Engineering Materials 2021;884:149–156.

Marlinda L, Prajitno DH, Roesyadi A, Gunardi I, Mirzayanti YW, Muttaqii MA, et al. Biofuel from hydrocracking of Cerbera manghas oil over Ni-Zn/HZSM-5 catalyst. Ecletica Quimica 2022;47:17–39.

Arumugam M, Goh CK, Zainal Z, Triwahyono S, Lee AF, Wilson K, et al. Hierarchical HZSM-5 for Catalytic Cracking of Oleic Acid to Biofuels. Nanomaterials 2021 mar;11(3):747. https://doi.org/10.3390/nano11030747.

Hendra D, Wibowo S, Hastuti N, Wibisono H. Karakteristik Biodiesel Biji Bintaro Cerbera Manghas L dengan Proses Modifikasi. Jurnal Penelitian Hasil Hutan 2016 mar;34(1):11–21. https://doi.org/10.20886/jphh.2016.34.1.11-21.

Fasmawi Y, Widyaputri J, Marlinda L, Rahmi, Suryadri H. Effect of Hierarchical H-ZSM-5 and Fatty Acid Methyl Ester of Cerbera Manghas Oil to Hydrocarbons Liquid Product Composition in Catalytic Cracking Process. In: Proceedings of thethe 4th International Seminar on Fundamental and Application of Chemical Engineering (ISFAChE) Surabaya, Indonesia: Institut Teknologi Sepuluh Nopember; 2022. p. 1–6.

Barrón CAE, Melo-Banda JA, Dominguez JME, Hernández ME, Silva RR, Reyes TAI, et al. Catalytic hydrocracking of vegetable oil for agrofuels production using Ni–Mo, Ni–W, Pt and TFA catalysts supported on SBA-15. Catalysis Today 2011 may;166(1):102–110. https://doi.org/10.1016/j.cattod.2011.01.026.

Hancsók J, Kasza T, Kovács S, Solymosi P, Holló A. Production of bioparaffins by the catalytic hydrogenation of natural triglycerides. Journal of Cleaner Production 2012 oct;34:76–81. https://doi.org/10.1016/j.jclepro.2012.01.036.

Jimmy J, Roesyadi A, Suprapto S, Kurniawansyah F. Biofuel production over Fischer-Tropsch synthesis: effect of FeCo/meso-HZSM-5 catalyst weight on product composition and process conversion. EUREKA: Physics and Engineering 2021 nov;3(6):19–27. https://doi.org/10.21303/2461-4262.2021.001657.

Marlinda L, Al-Muttaqii M, Roesyadi A, Prajitno DH. Formation of hydrocarbon compounds during the hydrocracking of non-edible vegetable oils with cobalt-nickel supported on hierarchical HZSM-5 catalyst. IOP Conference Series: Earth and Environmental Science 2017 may;67:012022. https://doi.org/10.1088/1755-1315/67/1/012022.




DOI: http://dx.doi.org/10.12962/j20882033.v33i3.14200

Refbacks

  • There are currently no refbacks.


Creative Commons License

IPTEK Journal of Science and Technology by Lembaga Penelitian dan Pengabdian kepada Masyarakat, ITS is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.
Based on a work at https://iptek.its.ac.id/index.php/jts.